Wednesday, January 12, 2022

Acid

Acid (pronounced as-id)

(1) In chemistry, a compound usually having a sour taste and capable of neutralizing alkalis and reddening blue litmus paper, containing hydrogen that can be replaced by a metal or an electropositive group to form a salt, or containing an atom that can accept a pair of electrons from a base. Acids are proton donors that yield hydronium ions in water solution, or electron-pair acceptors that combine with electron-pair donors or bases; having a pH value of less than 7.

(2) In chemistry, any compound which easily donates protons (a Brønsted acid); any of a class of water-soluble compounds, having sour taste, that turn blue litmus red, and react with some metals to liberate hydrogen, and with bases to form salts; any compound that can accept a pair of electrons to form a covalent bond (a Lewis acid).

(3) A substance sour, sharp, or biting to the taste; tart; having the taste of vinegar.

(4) Something, as a remark or piece of writing, that is sharp, sour, or ill-natured.

(5) A slang term for the hallucinogenic drug Lysergic acid diethylamide (LSD).

(6) In metallurgy, noting, pertaining to, or made by a process in which the lining of the furnace, or the slag that is present; functions as an acid in high-temperature reactions in taking electrons from oxide ions: usually a siliceous material, as sand or ganister.

(7) Of or pertaining to an acid; acidic.

(8) In pop music, a genre that is a distortion (as if hallucinogenic) of an existing genre, as in acid house, acid jazz, acid rock etc.

1620-1630: From the French acide, from Latin acidus (sour, sharp, tart (and used also figuratively to suggest "disagreeable” etc)), adjective of state from acere (to be sour, be sharp) and akin to ācer (sharp) & acētum (vinegar), from aceō (I am sour); doublet of agita.  Root was the primitive Indo-European ak (be sharp, rise (out) to a point, pierce).

The figurative use (sour-tempered; acerbic) in English dates from 1775 and came to be applied to intense colors after 1916.  The process of the acid dye was invented in 1888 and used an acid bath. The “acid test” is American English from 1881, originally a quick way to distinguish gold from similar metals by application of nitric acid, it came to be used figuratively (and not always accurately) in the same senses as “litmus test”.  The “Acid drop”, a kind of hard sugar candy flavored with tartaric acid, was first sold in 1835, the noun “drop” applied in the sense of a lozenge.  The noun appeared in the 1690s, derived from the adjective and was originally applied (rather loosely) to just about any substance tasting like vinegar; the more precise parameters defined only in the early eighteenth century as the techniques of modern chemistry came to be refined.  In the chemical sense, the antonym is alkaline.  The term “acid rain” (highly acidic rain caused by atmospheric pollution) was in 1872 coined by Scottish chemist (Robert) Angus Smith (1817–1884) although it wouldn’t be for another hundred years before if came into general use.  Diana, Princess of Wales (1961–1997) coined a nickname for her step-mother, Raine Spencer (1929-2016): Acid Raine.  

Acid as a slang term for the hallucinogenic drug Lysergic acid diethylamide (LSD) dates from 1966.  From the same year “acid rock” was originally a descriptor applied to music performed by those who were tripping on LSD (or what they sounded like suggested they might be) but, as acid rockers, soon applied equally to the audience.  The adjective before long was bolted onto a wide variety of pop music (acid jazz, acid folk etc), acid house from 1988 probably the most enduring as a marketing term. 

LSD-25 Auto.

In an example of cross-breeding in marketing,"LSD-25 Auto" is a strain of weed.  The retailers recommend LSD-25 Auto to those who “love purple strains”, praising her “tightly packed trichomes”… “clustered around the hypnotic purple shining buds that have a stacked and long characteristic”.  Bag appeal” is said to be “on the next level” and able to “blast you into another dimension and keep you there”.  Being “mind-bending and certainly on the trippy side”, she’s said to be “best suited for smokers with a high tolerance to cerebral roller coasters and those who enjoy high concentration levels and spurts of creativity”.  For those still unsure, they caution that “novice smokers should take in moderation”.

Cutaway drawing of limited slip differential (LSD).

LSD is also the abbreviation for the limited slip differential, a device used in motor vehicles which allows a differential’s two output shafts to rotate at different speeds within a defined permissible difference in speed.  LSDs are used to improve traction under extreme conditions and the usual slang is “slippery-diff”.  LSD was also the historic abbreviation for the currency denominations used by UK prior to the decimalization of Sterling in 1971.  Although pre-1971 Sterling (based on there being 12 pennies to the shilling and 20 shillings to the pound) also used guineas, half crowns, threepenny bits, sixpences and florins, LSD referenced just the base units: pounds, shillings and pence.  The abbreviation LSD dates from Ancient Rome when a pound of silver was divided into 240 pence (or denarius) and the Latin currency denominations were librae, solidi, and denarii.  In veterinary science, LSD is also the standard abbreviation for lumpy skin disease, a viral disease of cattle and water buffalo.

Lindsay Lohan in Peter Thomas Roth’s campaign promoting Water Drench Hyaluronic Cloud Hydra-Gel Eye Patches.

The active ingredient in the patches is hyaluronic acid, a gooey, slippery substance produced naturally throughout the body and at its highest concentration in the eyes, joints and skin.  Best visualized as a lubricant, it works by providing a fluid cushion between tissues which would otherwise grind against each other.  As a lubricant, hyaluronic acid has remarkable properties, one teaspoon of the stuff able to absorb and retain some 6 US gallons (22¾ litres) of water, a reason why it’s used in the treatment of dry eyes and is a popular additive in in moisturizing creams, lotions, ointments and serums.  Hyaluronic acid is often produced by fermenting certain types of bacteria (rooster combs (the red, Mohawk-like growth on top of a rooster’s head and face) a common source) something the beauty industry dwells on less than the use to enhance the way skin stretches and flexes, reducing wrinkles.  It said also to be helpful in wound healing and the reduction in scarring.

Because of the popular association science fiction and gaming with toxic, flesh dissolving fluids (sometimes flowing through the veins of aliens) the word “acid” evokes horror in many but the body naturally produces many acids and it depends on these interacting with everything else to ensure good health and acids in many forms are in every diet.  An apple (a typical example containing up to 300 chemicals) for example includes pantothenic acid (B5), citric acid, tartaric acid & acetic acid while its taste depends on the concentration of malic acid.  Pantothenic is a combination of pantoic acid and β-alanine, the name pantohenic from the Greek πάντοθεν (pantothen) (from everywhere), the name chosen by chemists because, at least in tiny quantities, it’s present in almost all foods.  Familiar too is the pain-killer aspirin, now taken by many in low-dose form (100 mg or 1½ grains), a regime first recommended as a blood-thinner for those with certain risk factors for heart disease but later adopted by those impressed with the apparent protection offered against many internal cancers.  To a chemist, what we call the non-steroidal anti-inflammatory drug aspirin is acetylsalicylic acid (usually pronounced uh-seet-l-sal-uh-sil-ik as-id).  

Lysergic acid diethylamide

LSD, known colloquially as acid, is a drug known for its psychological effects. This includes altered awareness of surroundings, perceptions, and feelings as well as sensations and images that seem real though they are not.  It’s thus most often described as a hallucinogenic and the one which first generated a moral-panic although there has never been any evidence to support the stories which circulated telling cautionary tales of users leaping to their deaths from tall buildings, thinking themselves able to fly.  The urban myths persist to this day.

LSD was created in Basel in November, 1938 by Swiss chemist Albert Hofmann (1906–2008).  Dr Hofmann synthesized LSD after examining the constituents of the well-known medicinal plant Drimia maritima (squill) and the fungus ergot, the breakthrough moment apparently his understanding of the chemical structure of the squill's Scilla glycosides but the famous properties were discovered only serendipitously, his pharmaceutical research for a unrelated purpose.  It wasn't until 1943 that Dr Hofmann conducted any research on the possibilities LSD might offer using what he then regarded as side-effects.  In a long-known scientific tradition, he tested it on himself, thus enjoying the first acid-trip.

Having no bad trips, he continued the research and LSD (acronym for the German Lyserg-säure-diäthylamid) was in 1947 introduced as a commercial medication under the trade-name Delysid and intended for various psychiatric uses.  In the 1950s, the CIA thought the drug might be useful for mind control and chemical warfare, their tests conducted on young servicemen and students, usually without anything even close to informed consent.  Its possibilities interested psychiatrists and it was a popular subject in experimental research, the design of many of which would today appall ethics committees and terrify the lawyers.

President Richard Nixon (1913-1994; US president 1969-1974) explaining to congress aspects the message sent to the Congress on 17 June 1971, requesting the appropriation of an additional US$155 million for a “war on drugs”.  Egil Krogh (1939-2020 left) was deputy director of the Domestic Council and Dr Jerome Jaffe (b 1933, right) was hired to lead a new drug strategy and was usually referred to as Nixon’s “drugs tsar”.  Egil Krogh was later jailed for his involvement in the Watergate affair.

The subsequent recreational use in the Western world, an outgrowth of the 1960s counterculture, resulted in its worldwide prohibition in 1971, one of the most obvious casualties of the Nixon administration’s “war on drugs” which has around the world been for fifty-odd years waged with many consequences but little apparent effect on the demand for drugs, supply now at historically high levels, outpacing the increase in population.  Fifty years on, LSD remains popular though the extent of its use varies according to supply which tends to be dictated more by the economics of production and distribution than demand, the illicit drug business really preferring other substances because LSD is not addictive.  Of late there’s been much renewed interest in the possibilities offered by therapeutic hallucinogenics, the encouraging findings in DMT, LSD, mescaline & psilocybin research drawing in venture capital, the odd start-up picking up not only where things were left off in 1971 but working with more recently synthesised compounds.  Their difficulties are less scientific than regulatory.

Notable moments in Acid Rock

Todd Rundgren: A Wizard, a True Star (1973).

It’s not known if most listeners recovered from this but Todd Rundgren probably never did, his subsequent output so discursive that the many audiences he sought and sometimes gained never coalesced into a consistent following.   A Wizard, a True Star is there to be enjoyed as his psychedelic phase; just don’t expect more of the same.

Grateful Dead: Aoxomoxoa (1969).

Anthem of the Sun (1968) cast such a shadow that few dead heads list Aoxomoxoa as the band’s finest but none deny it’s the most psychedelic the Dead ever got in the studio.  The hippie-dippy vibe is of course more on display on many of the live releases (bootlegs and otherwise) but on Aoxomoxoa there are enough of the long, circular guitar lines for any tripper to keep tripping.  Unlike some of the European electronica which would follow, the Dead sound best through speakers rather than headphones but, at the time, the effect of Quadraphonic divided opinion.

The Jimi Hendrix Experience: Electric Ladyland (1968).

Not all of Electric Ladyland was as psychedelic as the reputation suggests but, spread over two records, there was room to move and psychedelia does at least tinge much of the blues for which this is remembered.  Some trippers however resist the epic length Voodoo Chile and go straight to side three of the original vinyl, setting the turntable to repeat.

Spirit: Twelve Dreams of Dr Sardonicus (1970).

Although not released until the era’s historic moment had passed with the implosion of the San Francisco ecosystem which fed the beast, Twelve Dreams Of Dr Sardonicus is the retrospective encapsulation of the psychedelic and is Spirit’s masterpiece.  Lyrically one long, strange trip, it’s also musically playful, mixing (rather than fusing) the most clichéd of the motifs of jazz, pop & rock.  This is acid rock’s period piece.

Pink Floyd: More (1969).

So much has Dark Side of the Moon (1973) loomed over Pink Floyd that their early work is neglected by all but a few.  In some cases the indifference is not undeserved but, influenced by the late Syd Barrett (1946-2006), before they were a staple of FM radio, Pink Floyd were certainly somewhere on the psychedelic spectrum and while The Piper At The Gates Of Dawn (1967) hints at it, their work in a trilogy of film soundtracks, More (1969), Zabriskie Point (1970) & Obscured by Clouds (1972) tracks the path of acid-rock.  The best approach is said to be to watch Zabriskie Point with the sound turned down while the album plays on repeat and a true aficionado will drop some acid a few minutes before putting on the headphones.



Sheryl Crow: There goes the neighborhood

Hey let's party
Let's get down
Let's turn the radio on
This is the meltdown
Get out the camera
Take a picture
The drag queens and the freaks
Are all out on the town
And cowboy Jane's in bed
Nursing a swollen head
 
Sunshine Sally and Peter Ustanov
Don't like the scene any how
I dropped acid on a Saturday night
Just to see what the fuss was about
Now there goes the neighborhood
 
The photo chick made to look sickly
Is standing in her panties in the shower
She plays the guitar in the bathroom
While the police dust her mother's plastic flowers
And Schoolboy John's in jail
Making a killing through the U.S. mail
 
Sunshine Sally and Peter Ustanov
Don't like the scene any how
I dropped acid on a Saturday night
Just to see what the fuss was about
Now there goes the neighborhood
 
This is the movie of the screenplay
Of the book about a girl who meets a junkie.
The messenger gets shot down
Just for carrying the message to a flunkie.
We can't be certain who the villans are 'cuz everyone's so pretty
But the afterparty's sure to be a wing-ding as it moves into your city
 
Sunshine Sally and Peter Ustanov
Don't like the scene any how
I dropped acid on a Saturday night
Just to see what the stink was about
Now there goes the neighbourhood.

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