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Sunday, April 21, 2024

Deliquesce

Deliquesce (pronounced del-i-kwes)

(1) In physical chemistry, to become liquid by absorbing moisture from the atmosphere and dissolving in it (best illustrated by the behavior of certain salts).

(2) To melt away; to disappear (used literally & figuratively).

(3) In botany, branching so the stem is lost in branches (as is typical in deciduous trees).

(4) In mycology (of the fruiting body of a fungus), becoming liquid as a phase of its life cycle.

1756: From the Latin dēliquēscere (to become liquid), the construct being dē- + liquēscere (to liquefy; liquescent).  In scientific literature, the adjective deliquescent (liquefying in air) is the most commonly used form.  It was from the Latin deliquescentem (nominative deliquescens), present participle of deliquescere (to melt away), the construct being de- + liquesco (I melt) and familiar in French also as déliquescent.  The de- prefix was from the Latin -, from the preposition (of, from (the Old English æf- was a similar prefix).  It imparted the sense of (1) reversal, undoing, removing, (2) intensification and (3) from, off.  In French the - prefix was used to make antonyms (as un- & dis- function in English) and was partially inherited from the Old and Middle French des-, from the Latin dis- (part), the ultimate source being the primitive Indo-European dwís and partially borrowed from Latin dē-.  The figurative sense of “apt to dissolve or melt away” was in use by 1837 while the verb deliquesce appears not to have been used thus until the late 1850s.  In scientific literature, the adjective deliquescent (liquefying in air) is the most commonly used form.  It was from the Latin deliquescentem (nominative deliquescens), present participle of deliquescere (to melt away), the construct being de- + liquesco (I melt) and familiar in French also as déliquescent.  The figurative sense of “apt to dissolve or melt away” was in use by 1837 while the verb deliquesce appears not to have been used thus until the late 1850s.    Deliquesce, deliquesced & deliquescing are verbs, deliquescent is an adjective, deliquescence is a noun and deliquescently is an adverb; the noun plural is deliquescences.

Deliquesce 1, oil on canvas by Tammy Flynn Seybold (b 1966).

This was the first in the Deliquesce Series, a group of works exploring the themes of transformation and conservation of energy in human forms, the artist noting being intrigued by the deceptively ephemeral nature of materials: “We think of objects - human forms included - as decaying, degrading or ‘disappearing’ but, as we know from the laws of thermodynamics, all energy is conserved - like matter, it is merely transformed from one form to another.  This work, painted with pastel-hued oils was made directly from a live model, the drips allowed organically to happen from her languid form and by using light, bright hues, I hoped to bring a spirit of optimism to this transformative process.

A footnote to the addition of deliquesce to scientific English is a tale of the chance intersection of politics and chemistry.  Dr Charles Lucas (1713–1771) was an Anglo-Irish physician who held the seat of Dublin City in the Irish Parliament and was what now would be called “a radical”, dubbed at the time “Irish Wilkes” (a nod to the English radical politician John Wilkes (1725–1797).  His early career was as an apothecary and he was shocked discover the fraud and corruption which permeated the industry and in an attempt to reform the abuses published A Short Scheme for Preventing Frauds and Abuses in Pharmacy (1735) which much upset his fellow apothecaries who were the beneficiaries of the crooked ways but the parliament did respond and created legislation regulating standards in medicines and providing for the inspection of the products; it was the first of its kind in the English-speaking world and the ancestor of the elaborate framework of rules today administered by entities such as the US FDA (Food & Drug Administration.  Encouraged, he later published Pharmacomastix, or the Office, Use, and Abuse of Apothecaries Explained (1741), the contents of which were used by the parliament to make certain legislative amendments.

However, as well as a radical, Lucas was a idealist and while the establishment was content to support him in matter of pills and potions, when he intruded into areas which disturbed the political equilibrium, they were less tolerant and, facing imprisonment, Lucas fled to the continent where he’d decided to study medicine, graduating as a doctor in 1752.  One of his first projects as a physician was a study of the composition of certain mineral waters, substances then held to possess some remarkable curative properties (something actually not without some basis).  To undertake his research he visited a number of sites including Spa, Aachen in what is now North Rhine-Westphalia and Bath in the English county of Somerset.  The material he assembled and published as An Essay on Waters. In three Parts: (i) of Simple Waters, (ii) of Cold Medicated Waters, (iii) of Natural Baths (1756) and it was in this work that the verb “deliquesce” first appeared.  Ever the “disturber” Dr Lucas’s tract upset the medical establishment in much the same way two decades earlier he’d stirred the enmity of the apothecaries, the cluster of physicians clustered around the Bath spa angered the interloper hadn’t consulted with them on a topic over which they asserted proprietorship.

Lindsay Lohan and her lawyer in court, Los Angeles, December 2011.

In chemistry, the companion word of deliquescence is hygroscopy, both describing phenomena related to the ability of substances to absorb moisture from the surrounding environment, but they differ in extent and behavior.  Hygroscopy refers to the ability of a substance to absorb moisture from the air when exposed; hygroscopic substances can attract and hold water molecules onto their surface but tend not to dissolve.  Many salts behave thus and a well-known example of practical application is the silica gel, which, in small porous packages, is often used as a desiccant to absorb moisture in packaging. Deliquescence can be thought of an extreme form of hygroscopy (hydroscopy taken to its natural conclusion) in that a substance which deliquesces not only absorbs moisture from the air but also absorbs it to the point where it dissolves completely in the absorbed water, forming a solution.  In the natural environment, this happens most frequently when the relative humidity of the surrounding air is high and the classic deliquescent substances are salts like calcium chloride, magnesium chloride, zinc chloride, ferric chloride, carnallite, potassium carbonate, potassium phosphate, ferric ammonium citrate, ammonium nitrate, potassium hydroxide, & sodium hydroxide.  Presumably because deliquescence is the extreme form of hydroscopy it was the former which came to be used figuratively (dissolving into “nothing”) while the latter did not.

At the chemical level, hygroscopy (a class in which scientists include deliquescence as a sub-set) describes the phenomenon of attracting and holding water molecules via either absorption or adsorption (the adhesion of a liquid or gas on the surface of a solid material, forming a thin film on the surface.) from the surrounding environment.  Hygroscopy is integral to the biology of many plant and animal species' attainment of hydration, nutrition, reproduction and/or seed dispersal.  Linguistically, hygroscopy is quirky in that the construct is hygro- (moisture; humidity), from the Ancient Greek ὑγρός (hugrós) (wet, moist) + -scopy (observation, viewing), from the Ancient Greek σκοπέω (skopéō) (to see (and the source of the Modern English “scope”) yet unlike other forms suffixed by “-scopy”, it no longer conveys the sense of “viewing or imaging”.  Originally that was the case, a hygroscope in the late eighteenth century understood as a device used to measure humidity but in a wholly organic way this use faded (“dissolving deliquescently to nothing” as it were) while hygroscopic (tending to retain moisture) & hygroscopy (the ability to do so) endured.  The modern instrument used to measure humidity is hygrometer, the construct being hygro- + -meter (the suffix from the Ancient Greek μέτρον (métron) (measure) used to form the names of measuring devices.

Sunday, February 13, 2022

Caffeine

Caffeine (pronounced ka-feen, kaf-een or kaf-ee-in)

A white, crystalline, bitter alkaloid with the chemical compound C8H10N4O2.

1830: From the French caféine, the construct being café (coffee) + ine (the chemical suffix).  The earlier German was kaffein, from kaffee (coffee); the adjective is caffeinic.  Technically, caffeine is a trimethyl-derivative of xanthine, a coining as Kaffein in 1830, from German Kaffein, by German analytical chemist Friedlieb Ferdinand Runge (1794–1867).  He chose the name because the alkaloid was found in coffee beans; its presence accounting for the stimulating effect of coffee and tea.  The noun caffeinism was coined as medical jargon in 1880 to describe the "morbid state produced by prolonged or excessive exposure to caffeine" although the condition had for centuries been noted by doctors and others.

Of coffee

Caffeine's molecular structure.

Methyltheobromine (or caffeine) is a central nervous system stimulant and the most widely consumed psychoactive drug which works, inter alia, by reversibly blocking the action of adenosine on its receptor and consequently prevents the onset of adenosine-induced drowsiness.  Caffeine is a bitter, white crystalline purine, a methylxanthine alkaloid, chemically related to the adenine and guanine bases of DNA and ribonucleic acid RNA.

Human caffeine consumption is said to date from circa 3000 BC when, according to Chinese legend, the mythological Emperor Shennong (Divine Farmer) serendipitously invented tea, a story derived from an early book on the history of tea.  Coffee drinking first became common in the mid-fifteenth century in the Sufi monasteries of Yemenin Arabia and it spread first to North Africa and by the sixteenth century was widely consumed throughout the Middle East, Persia and Asia Minor.  The first European coffee houses were in Italy and they soon became common throughout the continent.

Voltaire (1760) by Théodore Gardelle (1722–1761); he doubtlessly agreed with de Fontenelle.

In its pure form, caffeine can be fatal in tiny quantities although in the form usually enjoyed, coffee, one would need to drink over a hundred cups in a day to approach toxicity.  Voltaire (1694–1778), often at the Café de Procope in Paris, drank sometimes as many as forty cups a day, enjoying it so much he ignored the advice of his doctors to stop.  He lived to eighty-four but there’s no evidence the often attributed quotation: It may be poison, but I have been drinking it for sixty-five years, and I am not dead yet was his.  The more likely source is French author Bernard Le Bovier de Fontenelle (1657–1757) whose actual words were: I think it must be [a slow poison], for I’ve been drinking it for eighty-five years and am not dead yet.”   Fontenelle died a month short of his hundredth birthday.

Depiction of seventeenth century London coffee house.

Whatever the concern about coffee the drink, the coffee house the place attracted its own concerns.  There’s some evidence coffee houses were welcomed by the authorities when first they became popular in seventeenth century London because they seemed a desirable alternative to the ale house where men would drink beer and later gin, leading to all the notorious social ills.  However, it seemed soon to kings and ministers that while having drunken men brawl or beat their wives was hardly good, it was a more manageable problem than having them cluster, share the newly available cheap newspapers and pamphlets, talk and think.  Men taking and thinking might lead to them getting ideas which was worse than them fighting in the street and government made repeated attempts to suppress the coffee shops.  Ultimately, caffeine prevailed.

Johann Sebastian Bach (circa 1760) by Johann Eberhard Ihle (1727–1814).

On the continent, the Habsburgs were no more impressed than the Stuarts in England, the government there encouraging the idea of coffee was a subversive societal vice and there was something of a minor moral panic among good citizens disturbed at the corrupting influences of such places.  This didn’t amuse a German composer famously associated with the late Baroque, JS Bach (1685–1750) who was fond of taking his frequent shots in his favorite coffee shops and, although never noted for his light-heartedness, he took an amusing poem mocking the public’s concerns, written by his frequent collaborator Christian Friedrich Henrici (1700–1764; pen name Picander), and set it to music as Schweigt stille, plaudert nicht (Be still, stop chattering).  Composed between 1732-1735, it’s usually called the Coffee Cantata, although, it’s really a comic operetta.  A satirical commentary, the work makes fun of the concerns respectable folk had about coffee and coffee houses.  In Vienna as in London, caffeine triumphed.

Despite the joys of a Bach cantata and the persuasive (if misattributed) endorsement of Voltaire, the killjoy editors of the Diagnostic and Statistical Manual of Mental Disorders (DSM) weren’t sure ordinary folk could be trusted to decide how many cups of coffee daily to enjoy and declared more research was needed.  They often conclude more research is needed.  Strangely, the DSM’s editors appear to be less trusting than most clergy, caffeine a drug to which even normally condemnatory priests, rabbis and mullahs don’t object, the only famously abstemious among the major faiths being the Church of Latter-Day Saints (the Mormons), the Seventh-Day Adventists and the Rastafarians, the last perhaps a surprise given how well a long black complements some good weed.

Simple pleasure: the long black.

Widely consumed, caffeine is a psychoactive drug which produces its psychomotor stimulant and reinforcing effects through antagonism at adenosine receptors and indirect effects on dopaminergic neurotransmission.  The editors of DSM-5 (2013) were prepared to concede consumption of caffeine at recommended dietary doses is usually at least harmless and may even have some benefits such as the enhancement of analgesia but do caution some may experience caffeine-related health effects and functional impairment and that this can manifest in different people at different levels of consumption.  Higher doses can produce dysphoric subjective effects and caffeine intoxication, including restlessness, nervousness, insomnia and an irregular heartbeat.  It’s also associated in some with gastrointestinal problems, urinary incontinence and anxiety, use during pregnancy said to be associated with especially poor outcomes.

Lindsay Lohan leaving Coffee Bean, Los Angeles, December 2007.

Cold turkey may not be the solution either, the editors documenting withdrawal symptoms which some may experience if abruptly discontinuing regular use, including headaches, fatigue, irritability, a depressed mood, difficulty concentrating, and even flu-like symptoms, the DSM-5 codifying the conditions as (1) caffeine intoxication, (2) caffeine withdrawal, (3) caffeine-induced anxiety disorder and (4), caffeine-induced insomnia.  These are listed as the potential diagnoses when symptoms cause clinically significant distress or impairment and, because some individuals report an inability to reduce their consumption despite clinically significant problems even after seeking treatment, caffeine consumption can be said to lead to substance dependence.

Caffeine is an essential part of the recommended pro ana breakfast.

Thus the DSM-5 proposed three necessary diagnostic criteria for caffeine use disorder: (1) a persistent desire or unsuccessful efforts to reduce or control caffeine use, (2) continued caffeine use despite knowledge of (it’s not specified if an explicit acknowledgment is needed) having a persistent or recurrent physical or psychological problem that is likely to have been caused or exacerbated by caffeine and (3), withdrawal, as manifested by the characteristic withdrawal syndrome for caffeine, or caffeine or a closely related substance being taken to relieve or avoid withdrawal symptoms. Six additional diagnostic criteria included in other substance use disorders, such as craving, tolerance, and taking caffeine in larger amounts or over a longer period of time than intended, were also included as markers for greater severity beyond the three key criteria for caffeine use disorder.  Because caffeine is so widely consumed, to reduce any potential for over-diagnosis, the proposed diagnostic strategy for caffeine, despite sounding onerous, is actually more conservative than for other substances.

One can see the attraction of energy drinks.

The editors did note the paucity of data relating to the prevalence and clinical significance of caffeine use disorder and the suspicion is the interest may have been triggered not the usual suspect, coffee, but the newer generation of energy drinks and diet supplements.  Previous research was apparently too focused on specific, small-subsets rather than the general populations, some of the studies so specialized as to be thought unrepresentative of the general population.  One (very small) study of caffeine use disorder in the United States (reported in the DSM-IV (1994)) found that 30% of caffeine consumers fulfilled the generic DSM-IV criteria for substance dependence as applied to caffeine but this fell to 10% under (the supposedly more realistic) DSM-5 criteria, a hint the concerns of clinical over-diagnosis do need to be taken seriously.  Again, the point was made that more research is required, the extent to which caffeine use disorder is associated with markers of clinical significance such as self-reported caffeine-related distress or impairment, psychological distress, sleep problems, or other drug use is wholly unknown.

The documented study the editors reviewed was the most thorough evaluation yet conducted of the prevalence, clinical significance and correlates of meeting proposed criteria for caffeine use disorder yet it was extensive enough only to inform future research and considerations regarding risk and differential diagnosis, technical points about the parameters of control group populations especially noted.  Despite the apparent lack of robustness, the editors were persuaded the findings did support the inclusion of caffeine use disorder in future editions of the DSM.  Although only a small percentage of sampled caffeine consumers met the proposed key diagnostic criteria, where the standards were met, there were clinically meaningful effects.

All reputable authorities recommend a caffeine intake of not more than 400 mg a day, or two long black coffees.  Many coffee fiends exceed this before breakfast is over.

Caffeine has become more interesting as a drug because of the late twentieth-century phenomenon of the energy drink, the interest not so much in the caffeine content which, can be much more or much less than a cup of coffee but because the pattern of consumption is, in certain sub-groups, so associated with strong alcohol, often on a 1:1 (ie 30-60 ml spirits to 250 ml energy drink) basis, a pattern well known with long-established mixers like Coca-Cola but now in both much greater volume and a much higher caffeine content.  It’s difficult to tell whether a problem has emerged because while the deaths associated with the combination attract attention, the aggregate numbers, impressionistically, seem small and may not be statistically significant.  There's even been the suggestion extreme variations in ambient temperature may have been an at least contributory factor in some deaths.

Sunday, July 2, 2023

Whisk

Whisk (pronounced wisk or hwisk)

(1) To move with a rapid, sweeping stroke.

(2) To sweep (dust, crumbs etc, or a surface) with a whisk broom, brush, or the like.

(3) To draw, snatch or carry etc; a generalized term meaning to move or do something nimbly or rapidly (often as “whisked away”, “whisked off” etc).

(4) To whip (eggs, cream etc.) to a froth using a whisk or other beating device.

(5) The an act of whisking; a rapid, sweeping stroke; light, rapid movement.

(6) As whisk broom, a device topped with a small cluster of grass, straw, hair or the like, used especially for brushing.

(7) A kitchen utensil, in the form of a bunch of (usually metal wire, plastic strands or (in the Far East) bamboo) loops held together in a handle and used for beating, blending or whipping eggs, cream; making souffles etc.  Modern whisks can also be electro-mechanical and “non-stick” whisks use a Teflon coating.

(8) The by-product of something which has been “whisked away”.

(9) A special plane used by coopers for evening a barrel’s chimes (the curved, outermost edge or rim at the top and bottom ends of the barrel, typically wider and thicker than the rest of the staves (the vertical wooden planks that form the sides)).

(10) In fashion, a kind of cape forming part of a woman's dress (sometimes detachable).

(11) In some card games, the act of sweeping the cards off the table after a trick has been won.

1325–1375: From the Middle English & Scots wysk (rapid sweeping movement), from the earlier Scots verbs wisk & quhisk, from the Old English wiscian (to plait) & weoxian (to clean with brush), from a Scandinavian source comparable to the Old Norse & Norwegian visk (wisp), the Swedish viska besom & wisp (to whisk (off)) and the Danish visk & viske (to wipe, rub, sponge) and related to the Middle Dutch wisch, the Dutch wis, the Old High German wisken (to wipe) & wisc (wisp of hay), the German Wisch, the Latin virga (rod, switch) & viscus (entrails), the Czech vechet (a wisp of straw), the Lithuanian vizgéti (to tremble), the Czech vechet (wisp of straw) and the Sanskrit वेष्क (veka) (noose) all thought from the Proto-Germanic wiskaz & wiskō (bundle of hay, wisp), from the primitive Indo-European weys- or weis (to turn; to twist).  The un-etymological wh-, noted since the 1570s, probably developed because it was expressive of the sound typically generated by the act of “whisking” something; the same evolution was noted in whip and the onomatopoeic whack and whoosh.  The device used in preparing food (implement for beating eggs etc) was first documented as “a whisk” in the 1660s although cooks had presumably been using such things for many years.  The verb developed in the late fifteenth century, the transitive sense from the 1510s while the familiar meaning “to brush or sweep (something) lightly over a surface” dates from the 1620s.  Whisk & whisking are nouns & verbs and whisked is a verb; the noun plural is whisks.

Variations on a theme of whisk.

Whisk is (almost) wholly unrelated to whisky & whiskey.  Dating from 1715, whisky was a variant of usque,an abbreviation of usquebaugh, from the Irish uisce beatha (water of life) or the Scots Gaelic uisge-beatha (water of life), ultimately a translation of the Medieval Latin aqua vītae (water of life (originally an alchemical term for unrefined alcohol)).  The form whiskybae has been obsolete since the mid eighteenth century.  The Scots and Irish forms were from the Proto-Celtic udenskyos (water) + biwotos (life), from biwos(alive).  The Old Irish uisce (water) was from the primitive Indo-European ud-skio-, a suffixed form of the root wed- (water; wet); bethu (life), from the primitive Indo-European gwi-wo-tut-, a suffixed form of gwi-wo-, from the root gwei- (to live). The noun plurals are whiskies & whiskeys.  Although iskie bae had been known in the 1580s, it appears unrelated to usquebea (1706), the common form of which was uisge beatha which in 1715 became usquebaugh, then whiskeybaugh & whiskybae, the most familiar phonetic form of which evolved as “usky”, influencing the final spellings which remain whisky & whiskey.  Wisely, the Russians avoided the linguistic treadmill, the unchanging vodka freely translated as “little water”.  The exception was the “whisky”, a small carriage (technically a “light gig” to coach-builders) which was from the verb whisk, the idea being something in which one was “whisked quickly around” the lightweight carriages being faster than most.  Chefs also caution home cooks not to confuse “whisky butter” (A concoction made of whisky, butter & sugar) with “whisked butter” which is butter which has been whisked.

Lindsay Lohan Oreos

Lindsay Lohan in The Parent Trap (1998).

Whether it was already something widely practiced isn’t known but Lindsay Lohan is credited with introducing to the world the culinary novelty Oreos & peanut butter in The Parent Trap.  According to the director, it was added to the script “…for no reason other than it sounded weird and some cute kid would do it."  Like some other weirdnesses, the combination has a cult following and for those who enjoy peanut butter but suffer arachibutyrophobia (the morbid fear of peanut butter sticking to the roof of one’s mouth), Tastemade’s have provided a recipe for Lindsay Lohan-style Oreos with a preparation time (including whisking) of 2 hours.  They take 20 minutes to cook and in this mix there are 8 servings (scale ingredients up to increase the number of servings).

Ingredients

2 cups flour
1 cup unsweetened cocoa powder (plus more for dusting)
¾ teaspoon kosher salt
1 ¼ cups unsalted butter (at room temperature)
¾ cup sugar
1 teaspoon vanilla extract
Powdered sugar, for dusting

Filling Ingredients

½ cup unsalted butter, at room temperature
¼ cup unsweetened smooth peanut butter
1 ½ cups powdered sugar
1 teaspoon vanilla extract
A pinch of kosher salt (omit if using salted peanut butter)

Filling Instructions

(1) With a stand mixer fitted with a paddle attachment, the butter & peanut butter until creamy.

(2) Gradually add powdered sugar and beat to combine, then beat in vanilla and salt.

Whisking the mix.

Instructions

(1) Preheat the oven to 325°F (160°C). Line two baking sheets with parchment paper.

(2) In small bowl, whisk together flour, cocoa powder & salt.

(3) In a stand mixer fitted with a paddle attachment, cream together the butter and sugar until light and fluffy.  Mix in the vanilla extract. With the mixer running on low speed, add the flour mixture and beat until just combined (it should remain somewhat crumbly).

(4) Pour mixture onto a work surface and knead until it’s “all together”; wrap half in plastic wrap and place in refrigerator.

(5) Lightly dust surface and the top of the dough with a 1:1 mixture of cocoa powder and powdered sugar.

(6) Working swiftly and carefully, roll out dough to a ¼-½ inch (6-12 mm) thickness and cut out 2 inch (50 mm) rounds.  Transfer them to the baking sheets, 1 inch (25 mm) apart (using a small offset spatula helps with this step). Re-roll scraps and cut out more rounds, the repeat with remaining half of the dough.

(7) Bake cookies until the tops are no longer shiny ( about 20 minutes), then cool on pan for 5 minutes before transferring to wire rack completely to cool.

(8) To assemble, place half the cookies on a plate or work surface.

(9) Pipe a blob of filling (about 2 teaspoons) onto the tops of each of these cookies and then place another cookie on top, pressing slightly but not to the extent filled oozes from the sides.

(10) Refrigerate for a few minutes to allow the filling to firm up.  Store in an air-tight container in refrigerator.

The manufacturer embraced the idea of peanut butter Oreos and has released versions, both with the classic cookie and a peanut butter & jelly (jam) variation paired with its “golden wafers”.  As well as Lindsay Lohan’s contribution, Oreos have attracted the interest of mathematicians.  Nabisco in 1974 introduced the Double Stuf Oreo, the clear implication being a promise the variety contained twice crème filling supplied in the original.  However, a mathematician undertook the research and determined Double Stuf Oreos contained only 1.86 times the volume of filling of a standard Oreo.  Despite that, the company survived the scandal and the Double Stuf Oreo’s recipe wasn’t adjusted.

Scandalous in its own way was that an April 2022 research paper published in the journal Physics of Fluids wasn’t awarded that year’s Ig Nobel Prize for physics, the honor taken by Frank Fish, Zhi-Ming Yuan, Minglu Chen, Laibing Jia, Chunyan Ji & Atilla Incecik, for their admittedly ground-breaking (or perhaps water-breaking) work in explaining how ducklings manage to swim in formation.  More deserving surely were Crystal Owens, Max Fan, John Hart & Gareth McKinley who introduced to physics the discipline of Oreology (the construct being Oreo + (o)logy).  The suffix -ology was formed from -o- (as an interconsonantal vowel) +‎ -logy.  The origin in English of the -logy suffix lies with loanwords from the Ancient Greek, usually via Latin and French, where the suffix (-λογία) is an integral part of the word loaned (eg astrology from astrologia) since the sixteenth century.  French picked up -logie from the Latin -logia, from the Ancient Greek -λογία (-logía).  Within Greek, the suffix is an -ία (-ía) abstract from λόγος (lógos) (account, explanation, narrative), and that a verbal noun from λέγω (légō) (I say, speak, converse, tell a story).  In English the suffix became extraordinarily productive, used notably to form names of sciences or disciplines of study, analogous to the names traditionally borrowed from the Latin (eg astrology from astrologia; geology from geologia) and by the late eighteenth century, the practice (despite the disapproval of the pedants) extended to terms with no connection to Greek or Latin such as those building on French or German bases (eg insectology (1766) after the French insectologie; terminology (1801) after the German Terminologie).  Within a few decades of the intrusion of modern languages, combinations emerged using English terms (eg undergroundology (1820); hatology (1837)).  In this evolution, the development may be though similar to the latter-day proliferation of “-isms” (fascism; feminism et al).  Oreology is the study of the flow and fracture of sandwich cookies and the research proved it is impossible to split the cream filling of an Oreo cookie down the middle.

An Oreo on a rheometer.

The core finding in Oreology was that the filling always adheres to one side of the wafer, no matter how quickly one or both cookies are twisted.  Using a rheometer (a laboratory instrument used to measure the way in which a viscous fluid (a liquid, suspension or slurry) flows in response to applied forces), it was determined creme distribution upon cookie separation by torsional rotation is not a function of rate of rotation, creme filling height level, or flavor, but was mostly determined by the pre-existing level of adhesion between the creme and each wafer.  The research also noted that were there changes to the composition of the filling (such as the inclusion of peanut butter) would influence the change from adhesive to cohesive failure and presumably the specifics of the peanut butter chosen (smooth, crunchy, extra-crunchy, un-salted (although the organic varieties should behave in a similar way to their mass-market equivalents)) would have some effect because the fluid dynamics would change.  The expected extent of the change would be appear to be slight but until further research is performed, this can’t be confirmed.  The 33rd First Annual Ig Nobel Prize ceremony will (as a webcast) happen on Thursday 14 September 2023, at 18:00 pm (US eastern time).

Tuesday, May 17, 2022

Parsec

Parsec (pronounced pahr-sek)

A unit of astronomical length, based on the distance from Earth at which a star would have a parallax of one second of arc which is equivalent to 206,265 times the distance from the earth to the sun or 3.26 light-years.  Its lineal equivalent is about 19.1 trillion miles (30.8 trillion km).

1913: The construct was par + sec, derived from parallax + second.  Parallax is from the Middle French parallaxe, from the Ancient Greek παράλλαξις (parállaxis) (alteration) from παραλλάσσω (parallássō) (to cause to alternate) from λλάσσω (allássō) (to alter) from λλος (állos) (other).  Second, in the sense of time, is from the Middle English secunde & seconde, borrowed from the Old French seconde, from the Medieval Latin secunda, short for secunda pars minuta (second diminished part (of the hour)). Parsec is a noun; the noun plural is parsecs.

Distance in space

The parsec (pc) is a unit of length used to measure large distances to astronomical objects outside the Solar System.  A parsec is defined as the distance at which one astronomical unit subtends an angle of one arc second, which corresponds to 648000 astronomical units.  The nearest star to Earth, Proxima Centauri, is about 1.3 parsecs (4.2 light-years) from the Sun.

The parsec unit appears first to have been suggested in 1913 by the English astronomer Professor Herbert Hall Turner (1861-1930).  It was invented to permit calculations of astronomical distances using only raw observational data and is thus the default unit of measure in astronomy and astrophysics although the more-easily understood light-year is preferred by lay-persons.  While useful to describe the comparatively short distances within the Milky Way, multiples of parsecs are needed to map the wider universe including kiloparsecs (kpc) for objects immediately beyond the Milky Way and megaparsecs (Mpc) for more distant galaxies.  Gigaparsecs (Gpc) are used to measure the quasars and galaxies which exist at the extreme edge of the known universe; the particle horizon (the boundary of the observable universe) has a radius of about 14.0 Gpc (46 billion light-years).

Although in use for more than a century, the parsec wasn’t formally defined until August 2015 when the International Astronomical Union (IAU) which, as part of the definition of a standardized absolute and apparent bolometric magnitude scale, noted the existing explicit definition of the parsec as exactly 648000 astronomical units, or approximately 3.08567758149137×1016 metres.

Hubble telescope image of star-forming region in the Carina Nebula.  As photographed, the gas and dust cluster is about .889 of a parsec (2.9 light-years) tall.

Thursday, February 10, 2022

Doppelganger

Doppelganger (pronounced dop-uhl-gang-er or daw-puhl-geng-er (German))

(1) In legend, a ghostly apparition of a living person, especially one that haunts such a person.

(2) A counterpart of a living person, identical in appearance; a person remarkably similar in appearance to another.

(3) In the pop-culture fantasy genre, a monster that takes the forms of people, usually after killing them.

(4) An evil twin (often as alter ego)

1826 (1824 as a German word in English): From the German Doppelgänger, literally "double-goer" or “double walker” originally with a ghostly sense.  Although now less common, it was once sometimes the practice to use the half-English spelling doubleganger.  Doppel was from doppelt (double), from doppeln (double (made up of two matching or complementary elements)), from the Old French doble (to double), from the Latin dūplus, from the Proto-Italic dwiplos, the construct being duo (two) +‎ plus, from the Old Latin plous, from the Proto-Italic plous, from the primitive Indo-European pleh- & pelhu- (many) and cognate with the Ancient Greek πολύς (polús) (many) and the Old English feolo (much, many).  It was influenced by the Ancient Greek διπλόος (diplóos) (double), the construct being δι- (di-), from δύο (dúo) (two), + -πλόος (-plóos) (-fold) and the Proto-Germanic twīflaz (doubt). A doublet of Zweifel.  Gänger was from Middle High German genger (to go, to walk), the construct being Gang +‎ -er.  Gang was from the Middle High German ganc, from the Old High German gang, from the Proto-Germanic gangaz (pace, step, gait, walk) and cognate with the English gang.  The synonyms in the various senses include double, lookalike, dead-ringer & alter ego.

Kim Jong-un, 2019-2020.

Rumors that Kim Jong-un (b circa 1994, Supreme Leader of the Democratic People’s Republic of Korea (North Korea, the DPRK) since 2011) was incapacitated with (unspecified) health problems spiked in late 2021 when he appeared looking notably thinner than in his appearances only months earlier, the conspiracy theory hinging on the idea the part of the Supreme Leader was being played by a doppelganger.  Most speculation centered on Mr Kim’s apparently chronic obesity, chain smoking and legendarily enthusiastic intake of his favorite Swiss cheese, some suggesting the doppelganger would fulfill the role until a team of foreign doctors working in secret restored the Supreme Leader to good working order while others opined he may actually be dead and the elite of the ruling Workers' Party of Korea (the WPA, a kind of cross between the a communist party and the Kim family’s holding company) was just buying time while they worked out what to do next.

Noted DPRK watchers, the National Intelligence Service (NIS), the Republic of Korea's (South Korea, the ROK) spy agency, dismissed the idea and said the new, sexy, slimmed-down Supreme Leader was real, their findings based on a comparison using facial recognition software, weight-tracking models and analysis of high-resolution video.  According to the NIS, Mr Kim’s weight which by 2019 had reached 142 kg (313 lb), less than a year later had further ballooned to around 146 kg (322 lb) while his appearances in late 2021 indicated a loss of between 20-25 kg (44-55 lb).  They added he appeared to be in rude good health.

Kim Jong-un, 2021.

If that’s true, the weight-loss could be accounted for either by Mr Kim’s desire to slim down for reasons of health or may be political, the DPRK facing one of its worst food shortages in many years and he may wish to convey the impression he’s sharing in the deprivations being suffered by his people.  Various seasonal factors would anyway have squeezed the food supply but the COVID-19 measures taken certainly exacerbated the problem, the closure of the borders inducing the sharpest economic contraction since the loss in the early 1990s of economic assistance from the Soviet Union.  The DPRK’s trade with its main trading partner, the People’s Republic of China (PRC), dropped by between 80-90% from pre-pandemic levels and the NIS noted it was the “mismanagement” of the economy which had caused inflation rates to surge beyond that afflicting all but a few other countries but, with a chronic shortage of ink and paper, the DPRK was unable to resort to the short-term expedient of printing money.  Still, things appear not actually on the point of collapse, ballistic missile tests continuing and the COVID-19 policy has, as stated by official DPRK propaganda, proved an outstanding success, Pyongyang confirming the country has suffered zero cases since the pandemic began.  It does seem to prove a “shoot to kill” border policy works, something a few Western politicians have long suspected and probably longed for.

Kim Jong-un looking at morning tea.

Targeted sanctions imposed in response to the regime’s nuclear weapons recalcitrance had already resulted in some humanitarian suffering but the closure of the PRC-DPRK border and has increased this by blocking shipments of grain, fertilizer and farming equipment.  Severe flooding caused by powerful typhoons in 2020 which so lowered that year’s harvest also had effects which lingered, crop yields again very low in 2021.  It had become so bad that in a rare public admission, Mr Kim in 2021 told a Worker’s Party meeting that the “people’s food situation is now getting tense” and his immediate policy switch was to order all citizens to devote all their effort to farming, making sure to secure “every grain” of rice.  With apparently all NGO and UN staff having left the country, most sources of foreign aid have evaporated and the DPRK is more dependent on its own resources than at any time since the end of the Korean War (1950-1953).  All this might explain Mr Kim’s weight-loss, although not yet obviously malnourished, he’s at least setting an example.

Manchu Tuan, Shenyang, PRC (left) and the Supreme Leader (right).

In general circulation, Kim Jong-un doppelgangers are not actually rare, at least two known to be available for hire from talent agencies.  Regardless of what happens in the DPRK, it may be a good gig because in 2012, satirical site The Onion named Kim Jong-un the world’s sexiest man, either because he was, in their words, “devastatingly handsome” or a nod to Henry Kissinger’s (b 1923; US secretary of state 1973-1977) claim (actually probably a boast) that “power is the ultimate aphrodisiac”.  The Onion’s winner in 2011 had been Syrian dictator Bashar al-Assad (b 1965; president of Syria 2000-) so the editors may have found Dr Kissinger persuasive.  Manchu Tuan sells kebabs in the north-eastern Chinese city of Shenyang and says business has boomed since this resemblance to Mr Kim appeared on social media and he has hired another cook to prepare the kebabs, much of his time now absorbed with customers taking selfies with him.

Donald Trump doppelganger: Dolores Leis Antelo, a farmer from Nanton, La Coruna, Spain.  The two are reportedly not related and have never met.

Shao Jianhua Changsha, Hunan, PRC and his queue of selfie-requesting customers.

Shao Jianhua, who five years ago moved from his native Zhejiang to Changsha, makes and sells meat pies with dried and pickled vegetables, a dish associated with costal Zhejiang.  His shop operates from a cluster near the university halls of residence and the students, although very fond of his highly-regarded pies, also request selfies, business having expanded since word spread of his resemblance to PRC president Xi Jinping (b 1953; PRC president 2013-).  Mr Shao, whose pies sell for 3.5 yuan (US$0.55) has increased production to 1,600 a day during peak season and the queues are frequently long.

The conspiracy theorists do apply some science to their subjects.  Of particular interest are ears, cosmetic surgeons noting that ears are so difficult to modify to match those of another person and that latex versions attached with surgical glue are the best solution for these purposes although even with these there are limitations.  It’s not the first time a head of government’s ears have attracted interest.  In 1939, Adolf Hitler (1889–1945; Führer of Germany 1933-1945) sent his court photographer Heinrich Hoffmann (1885–1957) with the party which in 1939 went to Moscow to execute the Nazi-Soviet Pact, his task, inter alia, to get a good shot of Comrade Stalin’s (1878-1953; Soviet leader 1924-1953) ear-lobes, the Führer wishing to be reassured his new (and temporary) ally’s lobes were “separate and Ayran” and not “attached and Jewish”.  He was satisfied with Hoffman’s evidence but that didn’t stop him later double-crossing Stalin.

Front and back of blood sample of prisoner #7 (Hess), “Spandau #7 Pathology SVC Heidelberg MEDDAC 1139.

The flight to England by Rudolf Hess (1894–1987; Deputy Führer 1933-1941) in 1941, an attempt to persuade the British to conclude the war on the eve of the invasion of Russia, was one of the strangest episodes of the war and whether or not his flight was approved by Hitler remained a matter of conjecture for decades although the available evidence does suggest the Führer was as shocked as everyone else.  Another conspiracy theory ran for years, that of whether the Hess the British produced for trial in Nuremberg (1945-1946) and who was subsequently imprisoned in Spandau until his suicide (other conspiracy theories explore this) in 1987 was actually a doppelganger.  Books with various explanations about why the British might have done this were written, including one by a doctor who examined Hess while a prisoner and couldn’t reconcile his physiology with the injuries he’s suffered while serving in the Imperial Army in the First World War.  Eventually even the suspicious authors conceded the incarcerated Hess was the real one and in 2019, after one of Hess’s hermetically sealed blood samples was discovered and subjected to a DNA analysis which found a 99.99% likelihood of a match with one of Hess’s living relatives.

Lindsay Lohan and body double during filming of Irish Wish (Netflix), scheduled for release in 2023.

The most obvious doppelgangers are "body doubles", actors used when filming scenes when, for whatever reason, the lead actor can't be used.  Such are the tricks and techniques of film production, the body doubles don't have to be even close to exact doppelgangers, they need only be vaguely similar though they often share some distinctive characteristic (such a long red hair).  Generally, body doubles are used for three reasons:

(1) Dangerous stunts: Body doubles with specific expertise are often hired to perform dangerous scenes, such as car chases, fight scenes, or jumps from great heights.

(2) Time constraints: In some cases, the lead actor or actress may not be available to film certain scenes due to scheduling conflicts.  In these situations, a body double can be used to film the scene in their place, allowing production to continue without delay.

(3) Privacy: In some instances, actors may not wish to appear in certain scenes, typically those involving nudity.  Sometimes contractual clauses include these stipulations.